Supported transition metal nanomaterials: Nanocomposites synthesized by ionizing radiation

• Published in: Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2017-03, Vol.132, p.52-64
• Main Authors: Clifford, D.M., Castano, C.E., Rojas, J.V.
• Format: Article
• Language: English
• Subjects: Addition polymerization; Aqueous solutions; Free radicals; Gamma irradiation; Gamma rays; Ionizing radiation; Irradiation; Nanocomposites; Nanomaterials; Nanoparticles; Oxidation; Particle size distribution; Particulate composites; Radiation; Radiation dosage; Radiation sources; Radiolysis; Reduction (metal working); Substrates; Supports; Synthesis; Transition metal nanoparticles
• ISSN: 0969-806X; 1879-0895
• DOI: 10.1016/j.radphyschem.2016.12.001

Nanostructures decorated with transition metal nanoparticles using ionizing radiation as a synthesis method in aqueous solutions represents a clean alternative to existing physical, chemical and physicochemical methods. Gamma irradiation of aqueous solutions generates free radicals, both oxidizing and reducing species, all distributed homogeneously. The presence of oxidant scavengers in situ during irradiation generates a highly reductive environment favoring the reduction of the metal precursors promoting seed formation and nanoparticle growth. Particle growth is controlled by addition of surfactants, polymers or various substrates, otherwise referred to as supports, which enhance the formation of well dispersed nanoparticles. Furthermore, the combination of nanoparticles with supports can offer desirable synergisms not solely presented by the substrate or nanoparticles. Thus, supported nanoparticles offer a huge diversity of applications. Among the ionizing radiation methods to synthesize nanomaterials and modify their characteristics, gamma irradiation is of growing interest and it has shown tremendous potential in morphological control and distribution of particle size by judiciously varying parameters including absorbed dose, dose rate, concentration of metal precursor, and stabilizing agents. In this work, major advances on the synthesis of supported nanoparticles through gamma irradiation are reviewed as well as the opportunities to develop and exploit new composites using gamma-rays and other accessible ionizing radiation sources such as X-rays. •Radiation synthesis of transition metals on various substrates has been reviewed.•Remarkable advantages of radiolytic synthesis over chemical routes are presented.•Most radiolytic synthesis reports use γ-rays but future focus on X-rays is expected.•Properties of synthesized nanomaterials can be tuned by dose, dose rate, etc.