Effects of diffusion and particle size in a kinetic model of catalyzed reactions

• Published in: Journal of catalysis 2009-04, Vol.263 (1), p.67-74
• Main Authors: Mattos, T.G., Aarão Reis, Fábio D.A.
• Format: Article
• Language: English
• Subjects: Back spillover; Catalysis; Catalysts; Chemical reactions; Chemistry; Desorption; Diffusion; Exact sciences and technology; General and physical chemistry; Kinetics; Scaling; Spillover; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2009.01.011

We study a model for unimolecular reaction on a supported catalyst including reactant diffusion and desorption, using analytical methods and scaling concepts. For rapid reactions, enhancing surface diffusion or increasing particle size favors the flux of reactants to the catalyst particles, which increases the turnover frequency (TOF). The reactant flux towards the support becomes dominant when the ratio of diffusion lengths in the catalyst and in the support exceeds a critical value. A peak in the TOF is obtained for temperature-dependent rates if desorption energy in the support ( E d ) exceeds those of diffusion ( E D ) and reaction ( E r ). Significant dependence on particle size is observed when the gaps between those energies are small, with small particles giving higher TOF. Slow reactions ( E r > E d ) give TOF monotonically increasing with temperature, with higher reactant losses in small particles. The scaling concepts can be extended to interpret experimental data and results of more complex models. In a simple model of reaction, diffusion, adsorption and desorption, the conditions for a net flux of reactants from the support to the catalyst are determined, with significant increase of the turnover frequency for small particles.