Pd‐Catalyzed versus Uncatalyzed, PhI(OAc)2‐Mediated Cyclization Reactions of N6‐([1,1′‐Biaryl]‐2‐yl)Adenine Nucleosides

The front cover artwork for Issue 21/2017 is provided by the Lakshman Group at The City College of New York (USA). The image shows the beautifully delicate architecture of Hawa Mahal, in Jaipur, as a symbol of the delicate balance of various factors in the described C−N bond formation of N6‐([1,1′‐b...

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Bibliographic Details
Published in:ChemCatChem 2017-11, Vol.9 (21), p.4017-4018
Main Authors: Satishkumar, Sakilam, Poudapally, Suresh, Vuram, Prasanna K., Gurram, Venkateshwarlu, Pottabathini, Narender, Sebastian, Dellamol, Yang, Lijia, Pradhan, Padmanava, Lakshman, Mahesh K.
Format: Article
Language:English
Subjects:
Chemical reactions
Nucleosides
Palladium
Online Access:Get full text
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Summary:The front cover artwork for Issue 21/2017 is provided by the Lakshman Group at The City College of New York (USA). The image shows the beautifully delicate architecture of Hawa Mahal, in Jaipur, as a symbol of the delicate balance of various factors in the described C−N bond formation of N6‐([1,1′‐biaryl]‐2‐yl)adenine nucleosides promoted by PhI(OAc)2 under both Pd‐mediated and uncatalyzed reaction conditions, which ultimately leads to relatively complex product structures. See the Full Paper itself at https://doi.org/10.1002/cctc.201700918. “The selectivity of C−N bond formation of N6‐([1,1′‐biaryl]‐2‐yl)adenine nucleosides promoted by PhI(OAc)2 under both Pd‐mediated and uncatalyzed reaction conditions can be modulated to produce either carbazolyl or aryl benzimidazopurinyl nucleoside derivatives.” This and more about the story behind the research featured on the front cover can be found in this issue's Cover Profile. Read the full text of the corresponding research at https://doi.org/10.1002/cctc.201700918.
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201701686