Solution-processed SnO2 thin film for a hysteresis-free planar perovskite solar cell with a power conversion efficiency of 19.2

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2017, Vol.5 (47), p.2479-2483
• Main Authors: Jung, Kwang-Ho, Seo, Ja-Young, Lee, Seonhee, Shin, Hyunjung, Park, Nam-Gyu
• Format: Article
• Language: English
• Subjects: Annealing; Capacitance; Efficiency; Electron transport; Energy conversion efficiency; Fluorine; Hysteresis; Photoelectric effect; Photoelectric emission; Photoluminescence; Photons; Photovoltaic cells; Photovoltaics; Solar power; Spin coating; Substrates; Temperature; Thin films; Tin; Tin dioxide; Tin oxide; Tin oxides
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c7ta08040a

A hysteresis-free and high-efficiency planar perovskite solar cell was developed using a solution-processed SnO 2 electron-transporting layer (ETL). Tin( iv ) isopropoxide dissolved in isopropanol (IPA) was spin-coated on a fluorine-doped tin oxide (FTO) substrate in a nitrogen atmosphere. The effects of annealing temperature and precursor concentration on the photovoltaic performance were systematically investigated. The annealing temperature was scanned from 100 °C to 500 °C, whereby the 250 °C-annealed SnO 2 film demonstrated the best performance along with negligible current-voltage hysteresis. The SnO 2 film annealed at 250 °C was X-ray amorphous, while it was observed to be nanocrystallite from SnO 2 annealed at 500 °C. The faster stabilization of the photocurrent and lower interfacial capacitance for the 250 °C-annealed SnO 2 than for the 500 °C-annealed one were responsible for the markedly reduced hysteresis. The photovoltaic performance and hysteresis were influenced by the precursor concentration, where a concentration of 0.1 M showed hysteresis-free higher performance among the concentrations investigated ranging from 0.05 M to 0.2 M owing to a larger and faster photoluminescence quenching. The planar (HC(NH 2 ) 2 PbI 3 ) 0.875 (CsPbBr 3 ) 0.125 perovskite that was formed on the 40 nm-thick, 0.1 M-based and 250 °C-annealed SnO 2 thin film delivered a power conversion efficiency (PCE) of 19.17% averaged out from the forward scan PCE of 19.40% and the reverse scan PCE of 18.93%. A hysteresis-free and high-efficiency planar perovskite solar cell was developed using a solution-processed SnO 2 electron-transporting layer (ETL).