Core-shell structured Si@Ni nanoparticles encapsulated in graphene nanosheet for lithium ion battery anodes with enhanced reversible capacity and cyclic performance

• Published in: Electrochimica acta 2018-03, Vol.265, p.348-354
• Main Authors: Cheng, Xing-Wang, Zhao, Dong-Lin, Wu, Lu-Lu, Ding, Ze-Wen, Hu, Tao, Meng, Shuo
• Format: Article
• Language: English
• Subjects: Anode material; Anodes; Batteries; Conductivity; Core-shell structure; Cycles; Discharge; Electrochemical analysis; Electrode materials; Electrodes; Encapsulation; Graphene; Graphene nanosheet; Ions; Lithium; Lithium-ion batteries; Lithium-ion battery; Nanocomposites; Nanoparticles; Nanosheets; Nickel plating; Rechargeable batteries; Shell stability; Silicon base alloys; Structural stability; Transmission electron microscopy; Voltammetry; X-ray diffraction
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2018.01.198

A Si-based alloy as the negative electrodes of the Lithium-ion batteries (LIBs) possesses the advantages of high discharge capacity and better safety, but low electronic conductivity and poor property limit Si-based anode materials to commercialize for the LIBs. In this article, in order to solve the problems of poor conductivity and cycling instability, core-shell structured Si/Ni nanoparticles encapsulated in graphene nanosheet (Si@Ni-NP@GNS) has been proposed to enhance the electronic conductivity and cycling stability. The nanocomposite was characterized by using the measures of X-ray diffraction and transmission electron microscopy. The Si nano-particles as centre of sphere were coated with interconnected GNS and nickel-plated layer. The electrochemical performance was tested by cyclic voltammetry and galvanostatic charge-discharge tests. The nanocomposite behaves excellent specific capacity, outstanding cycle stability and perfect rate capability, the results show a reversible charge capacity of 2005 mA h g−1 after 50 cycles, which are superior to those of Si@GNS anode and Si@Ni-NP anode. We can be sure that the enhanced electrochemical performance is due to the core-shell structure, which interconnected GNS and nickel-plated layer act as buffer compound to avoid the excessive volume expansion and the electrode pulverization. [Display omitted] •Si@Ni-NP@GNS was prepared by chemical nickel plating and thermal reduction.•GNS and nickel layer act as buffer compound to avoid the excessive volume expansion.•Si@Ni-NP@GNS electrode exhibits excellent electrochemical performances.