Quantitative analysis of improved bending fracture behavior of large-scale graphene monolayer-intervened flexible oxide thin films

Graphene has been recognized to be potentially useful in creating higher mechanical integrity of electronic components due to its intrinsically superior mechanical properties. Here, we introduce the enhanced bending fracture resistance of flexible inorganic thin films by incorporating a large-scale...

Full description

Saved in:
Bibliographic Details
Published in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018, Vol.6 (23), p.6125-6131
Main Authors: Choi, Hong Je, Kim, Da Bin, Kim, Moo Hyun, Lee, Gwan-Hyoung, Cho, Yong Soo
Format: Article
Language:English
Subjects:
Electronic components
Fracture toughness
Graphene
Mechanical properties
Monolayers
Parameters
Polyethylene terephthalate
Quantitative analysis
Substrates
Thick films
Thin films
Zinc oxide
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Graphene has been recognized to be potentially useful in creating higher mechanical integrity of electronic components due to its intrinsically superior mechanical properties. Here, we introduce the enhanced bending fracture resistance of flexible inorganic thin films by incorporating a large-scale graphene monolayer, using a typical example of transparent conducting oxide (TCO) materials, i.e. , Al-doped ZnO (AZO) thin films. The bending fracture behavior has not been available thus far due to the inefficient coverage of the graphene layer, and also particularly on the basis of the quantitative analysis of fracture parameters. A graphene monolayer of the ∼1 cm × 1 cm scale was successfully transferred onto a flexible polyethylene terephthalate (PET) substrate prior to sputter-deposition of thin films with variable film thicknesses ranging from 50 nm to 200 nm. The highlights of the substantial improvements are the crack-initiating strain of 1.64% and the fracture energy of 364.2 J m −2 , which were obtained for the graphene-intervened 200 nm-thick AZO films. These values correspond to respective improvements of ∼61% and ∼272% compared to the reference sample without graphene. Other parameters including the film strength and fracture toughness also support the enhanced bending fracture resistance caused by the graphene-modification.
ISSN:2050-7526
2050-7534
DOI:10.1039/C8TC00084K