Reinvestigation of quantum dot symmetry: the symmetric group of the 8-band k⋅p theory Hamiltonian

• Published in: Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2019, Vol.21 (1), p.1-14, Article 16
• Main Authors: Li, Wei, Sabel, Thomas M.
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Conduction; Conduction bands; Coupling; Eigenvectors; Electron spin; Hamiltonian functions; Hilbert space; Inorganic Chemistry; Lasers; Materials Science; Nanotechnology; Optical Devices; Optics; Photonics; Physical Chemistry; Quantum dots; Quantum theory; Representations; Research Paper; Self-assembly; Symmetry; Traveling salesman problem
• ISSN: 1388-0764; 1572-896X
• DOI: 10.1007/s11051-018-4448-3

Self-assembled semiconductor quantum dots, usually formed in pyramid or lens shapes, have an intrinsic geometric symmetry. However, the geometric symmetry of a quantum dot is not identical to the symmetry of the associated Hamiltonian. It is a well-accepted conclusion that the symmetric group of the Hamiltonians for both pyramidal and lens-shaped quantum dots is C 2v ; consequently, the eigenstate of the Hamiltonian is not degenerate because C 2v has only one-dimensional irreducible representations. In this paper, we show the above conclusion is wrong. Using the 8-band k  ·  p  theory model and considering the action of group elements on both spatial and electron spin parts of the wavefunction, we find the symmetric group of the Hamiltonian is the C 2v double group not C 2v . C 2v is the symmetric group of the spatial part of the conduction band Hamiltonian only when the inter-band coupling is totally ignored. Employing the C 2v double group symmetry, we prove that although the C 2v double group has both one-dimensional and two-dimensional irreducible representations, the eigenstates of the 8 × 8 Hamiltonian are always two-fold degenerate and that these degenerate states only correspond to the two-dimensional irreducible representation of the C 2v double group. The double group symmetry originates from the coupling between spatial potential and electron half spin. This coupling causes a full 2π rotation in the wavefunction space or the Hilbert space not equal to the unity operation. Finally, the connection between the two-fold degeneracy due to the C 2v double group symmetry and Kramers’ degeneracy due to the time inversion symmetry is explored.