Is Thermogravimetry an efficient alternative to gas chromatography in degree of biodiesel conversion?
This work aims to determine if thermogravimetry could be used to determine the degree of conversion of soybean oil to biodiesel without knowing the amount of ester in the sample, comparing the results with the values obtained by the standard method, gas chromatography. The syntheses were made using...
Saved in:
Published in: | Journal of thermal analysis and calorimetry 2019-02, Vol.135 (4), p.2591-2597 |
---|---|
Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | This work aims to determine if thermogravimetry could be used to determine the degree of conversion of soybean oil to biodiesel without knowing the amount of ester in the sample, comparing the results with the values obtained by the standard method, gas chromatography. The syntheses were made using homogeneous and heterogeneous catalysts, and the measures were made in triplicate on both pieces of equipment. The average values (%) obtained were 74.59 ± 0.58, 66.5 ± 1.62, 13.54 ± 0.32 by thermogravimetry and 74.09 ± 0.46, 62.08 ± 2.19, 17.07 ± 0.31 by gas chromatography. These data were statistically compared using
F
-test, and the result indicated that the thermogravimetry could be used as analytical technique to determine the degree of conversion of biodiesel, with the same reliability as gas chromatography. The thermogravimetry shows more advantages than gas chromatography, because it does not require organic solvent, following the Green Chemistry Principles, and it is already used to determine other thermal properties of biodiesel. |
---|---|
ISSN: | 1388-6150 1588-2926 |
DOI: | 10.1007/s10973-018-7364-y |