Effect of solvent for tailoring the nanomorphology of multinary CuCo2S4 for overall water splitting and energy storage

• Published in: Journal of alloys and compounds 2019-05, Vol.784, p.1-7
• Main Authors: Zequine, Camila, Bhoyate, Sanket, Wang, Fangzhou, Li, Xianglin, Siam, Khamis, Kahol, P.K., Gupta, Ram K.
• Format: Article
• Language: English
• Subjects: Catalysis; Chemical evolution; Chemical synthesis; Copper-cobalt oxide; Copper-cobalt sulfide; Crystal structure; Current density; Electrodes; Energy storage; Ethanol; Hydrogen evolution; Mesoporous 3D flower-like nanostructures; Morphology; Nanostructured materials; Oxygen evolution; Storage systems; Supercapacitor; Water splitting
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2019.01.012

Tailoring the nanomorphology of electrochemically active materials could significantly affect their resultant catalytic and charge storage performance. In this study, the nanostructured morphology of multinary CuCo2O4 and CuCo2S4 was tuned using a different volume concentration of water and ethanol resulting in different nano-shapes maintaining similar crystal structure. The electrocatalytic performance was analyzed for all the synthesized samples as the hydrogen (HER) and oxygen evolution catalyst (OER). The HER and OER study for CuCo2S4 sample synthesized using ethanol required a low overpotential of 158 mV to reach 10 mA/cm2 and 290 mV to achieve 20 mA/cm2, respectively. Furthermore, the electrolyzer cell using symmetrical electrodes required a low overall cell potential of 1.66 V to achieve a current density of 10 mA/cm2 and maintained stable performance for over 24 h, suggesting a promising bifunctional catalytic behavior. Furthermore, the synthesized samples were studied as electrodes for high-performance energy storage systems. The CuCo2S4 electrode showed an areal capacitance of 6.3 F/cm2 (3190.8 F/g) at a current density of 2 mA/cm2. The Ragone plot for the areal energy versus power density resulted to be 265 mWh/cm2 (132 Wh/kg) and 11.9 W/cm2 (5973 W/kg), respectively. Thus, from the overall study, it can be confirmed that tailoring morphology of nanostructured material such as CuCo2S4 could be a promising way for the advancement of energy generation and storage devices. •Effect of solvent on microstructure and electrochemical properties of CuCo2O4 and CuCo2S4 was studied.•CuCo2S4 required a low overpotential of 158 mV at 10 mA/cm2 for hydrogen evolution reaction.•CuCo2S4 required a low overpotential of 290 mV at 20 mA/cm2 for oxygen evolution reaction.•CuCo2S4 electrode showed an areal capacitance of 6.3 F/cm2 (3190.8 F/g) at a current density of 2 mA/cm2.