Synthesis and microwave absorption enhancement of yolk–shell Fe3O4@C microspheres

• Published in: Journal of materials science 2017-06, Vol.52 (11), p.6349-6361
• Main Authors: Tian, Chunhua, Du, Yunchen, Cui, Chunsheng, Deng, Zhiliang, Xue, Jianlei, Xu, Ping, Qiang, Rong, Wang, Ying, Han, Xijiang
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Classical Mechanics; Complex permittivity; Core loss; Crystallography and Scattering Methods; Dielectric loss; Frequency ranges; Impedance matching; Iron oxides; Magnetic permeability; Magnetic properties; Materials Science; Microspheres; Microstructure; Microwave absorption; Original Paper; Pollution abatement; Polymer Sciences; Reflection; Shells; Shortages; Silicon dioxide; Solid Mechanics
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-017-0866-3

Rational design on the microstructure of microwave-absorbing materials is paving the way for upgrading their performances in electromagnetic pollution prevention. In this study, a Fe 3 O 4 /C composite with unique yolk–shell microstructure (YS-Fe 3 O 4 @C) is successfully fabricated by a silica-assisted route. It is found that carbon shells in this composite can make up the shortages of Fe 3 O 4 microspheres in dielectric loss ability, while they may more or less attenuate the intrinsically magnetic loss of Fe 3 O 4 microspheres. The microwave absorption properties of YS-Fe 3 O 4 @C are evaluated in the frequency range of 2.0–18.0 GHz in terms of the measured complex permittivity and complex permeability. The results demonstrate that YS-Fe 3 O 4 @C can exhibit much better performance than bare Fe 3 O 4 microspheres and individual carbon materials, as well as core–shell Fe 3 O 4 /C composite (CS-Fe 3 O 4 @C), where strong reflection loss and wide response bandwidth can be achieved simultaneously. With an absorber thickness of 2.0 mm, the maximum reflection loss is −73.1 dB at 14.6 GHz and a bandwidth over −10.0 dB is in the range of 12.3–18.0 GHz. It can be proved that the unique yolk–shell microstructure is helpful to reinforce the dielectric loss ability and create an optimized matching of characteristic impedance in the composite.