Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks

The reactions of LiOH·H 2 O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li 2 (1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF) 2 } n ( 1 ), {[Li 3 (1,3,5-btc)(DMSO) 3 ](H 2 O)} n ( 2 ), {((CH 3 ) 2 NH)[Li 2 (1,...

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Bibliographic Details
Published in:Journal of inorganic and organometallic polymers and materials 2019-09, Vol.29 (5), p.1447-1456
Main Authors: Jiang, Zhi-Qiang, Du, Yu, Zhu, Xue-Jun, Lu, Jin, Huang, Zai-Chun, Li, Yu-Feng, Kang, Yao
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination polymers
Dimethyl sulfoxide
Inorganic Chemistry
Lithium
Organic Chemistry
Polymer Sciences
Structural analysis
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Summary:The reactions of LiOH·H 2 O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li 2 (1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF) 2 } n ( 1 ), {[Li 3 (1,3,5-btc)(DMSO) 3 ](H 2 O)} n ( 2 ), {((CH 3 ) 2 NH)[Li 2 (1,3,5-btc)(H 2 O)]} n ( 3 ), {((CH 3 ) 2 NH)[Li 2 (1,3,5-btc)(1,3,5-Hbtc)]} n ( 4 ), {((CH 3 ) 2 NH)[Li 2 (1,3,5-btc)]} n ( 5 ) and [Li 3 (1,3,5-btc)(H 2 O)] n ( 6 ) (DMSO = dimethyl sulphoxide, DMF =  N,N -dimethylformamide). Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. Graphical Abstract
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-019-01108-0