Modified laser‐fired contact process for efficient PERC solar cells

• Published in: Progress in photovoltaics 2019-12, Vol.27 (12), p.1092-1103
• Main Authors: Choi, Jae Myeong, Jung, Beomsic, Park, Jong‐Keuk, Kim, Won Mok, Lee, Doh‐Kwon, Jeong, Jeung‐hyun, Lee, Taek Sung, Choi, Jea‐Young, Ju, Byeong‐Kwon, Kim, Inho
• Format: Article
• Language: English
• Subjects: Alloying; Contact holes; Contact resistance; crystalline silicon solar cells; Electric contacts; Emitters; implied Voc; Laser damage; Lasers; laser‐fried contact; Open circuit voltage; PERC cell; Photovoltaic cells; pulsed laser; Silicon; Solar cells
• ISSN: 1062-7995; 1099-159X
• DOI: 10.1002/pip.3187

A laser‐fired contact (LFC) process is one of the techniques for making local electrical contacts at the rear side of passivated emitter and rear cell (PERC) solar cells. In the LFC process, opening of the passivated dielectric layers and alloying of Si and Al need to be made in a single step laser process. For this reason, the LFC process is accompanied by the loss of Al and the laser damage to the Si wafer. In this study, we present a novel multistep LFC process combining the conventional LFC and laser‐induced forward transfer (LIFT) processes. The modified LFC scheme we proposed consists of three steps: (a) opening of the passivation layers and partial alloying of Al‐Si, (b) additional deposition of Al on the local contact holes, and (c) post laser firing of the transferred Al. Applying the modified LFC process to the PERC cells of 1.0 cm2 of area, we demonstrate the effective recombination velocity of the laser‐processed wafers can be remarkably reduced while maintaining the low contact resistance. The best of the PERC solar cell fabricated by the modified LFC process exhibited an efficiency of 19.5% while the conventional LFC‐PERC cell showed 18.6%. The efficiency gains of the modified LFC‐PERC cells was largely contributed by the enhanced open circuit voltage (Voc) and fill factor (FF). We developed a modified LFC process by combining conventional LFC and LIFT technologies to reduce laser damage and enhance local BSF at the local contact holes while maintaining low contact resistances. The modified LFC process comprises three steps: (a) subthreshold LFC step, (b) LIFT step, and(c) PLF step, providing enhanced implied Voc and lower contact resistances in comparison with a conventional LFC process.