Benign Arylations of Dimethyl Itaconate via Heck–Matsuda Reaction Utilizing in‐Situ Generated Palladium on Aluminum Oxide

In situ generated palladium on aluminum oxide provides an active and efficient catalytic system for the preparation of arylmethylidene succinates using the Heck–Matsuda reaction. Beside the monoarylation the first examples of the biarylation of these monomers will be described. In situ generated pal...

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Bibliographic Details
Published in:European journal of organic chemistry 2020-01, Vol.2020 (1), p.127-135
Main Authors: Matelienė (née Dauksaîtė), Lauryna, Knaup, Jan, von Horsten, Frank, Gu, Xiaoting, Brunner, Heiko
Format: Article
Language:English
Subjects:
Aluminum
Aluminum oxide
Arylation
Arylmethylidene succinates
Dimethyl itaconate
Dimethylitaconate
Heck‐Matsuda reaction
Palladium
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Summary:In situ generated palladium on aluminum oxide provides an active and efficient catalytic system for the preparation of arylmethylidene succinates using the Heck–Matsuda reaction. Beside the monoarylation the first examples of the biarylation of these monomers will be described. In situ generated palladium on aluminium oxide provides an active and efficient catalytic system for the preparation of arylmethylidene succinates using the Heck–Matsuda reaction. Beside the monoarylation the first examples of the biarylation of this monomer will be described.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201901708