Torsions, low-frequency vibrations, and vibration–torsion (“vibtor”) levels in the m-chlorotoluene cation

Zero-electron-kinetic-energy (ZEKE) spectra are presented for m-chlorotoluene (mClT), employing different low-lying torsional and vibration–torsional (“vibtor”) levels of the S1 state as intermediates. The adiabatic ionization energy is determined to be 71 319 cm−1 ± 5 cm−1 (8.8424 ± 0.0006 eV). It...

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Bibliographic Details
Published in:The Journal of chemical physics 2020-02, Vol.152 (6), p.064303
Main Authors: Kemp, David J., Warner, Lewis G., Wright, Timothy G.
Format: Article
Language:English
Subjects:
Cations
Chlorotoluene
Fluorescence
Ionization
Spectra
Vibration
Citations: Items that this one cites
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