Electrical insulation performance of cross‐linked polyethylene/MgO nanocomposite material for ±320kV high‐voltage direct‐current cables

• Published in: Polymer composites 2020-05, Vol.41 (5), p.1936-1949
• Main Authors: Paramane, Ashish, Chen, Xiangrong, Dai, Chao, Guan, Honglu, Yu, Linwei, Tanaka, Yasuhiro
• Format: Article
• Language: English
• Subjects: Accumulation; Aging; Breakdown; Carbonyls; Cross-linked polyethylene; Direct current; Electric cables; Electric potential; Electrical insulation; Electrical resistivity; Magnesium oxide; Nanocomposites; Polyethylene; Space charge; Voltage
• ISSN: 0272-8397; 1548-0569
• DOI: 10.1002/pc.25509

Polymeric nanocomposite insulations are receiving the widespread attention of the electrical cable industry. This paper presents the electrical insulation performance of as‐received commercial 320 kV high‐voltage direct‐current (HVDC) cross‐linked polyethylene (XLPE)/MgO nanocomposite material with reference to the pure XLPE. The results of this commercial‐grade electrical insulation material are not reported hitherto. The scanning electron microscopy confirms the well‐dispersed nanofiller inside the polymer matrix. The DC electrical insulation performance is investigated by DC breakdown strength, space charge, DC electrical conductivity, and surface potential decay measurements. The test samples are subjected to the thermal aging at 135°C for 30 days. The un‐aged nanocomposite exhibits 20% higher DC breakdown strength, negligible hetero space charge accumulation, and the lower DC conductivity by one order than the un‐aged pure XLPE. Moreover, thermally aged nanocomposite shows more restraint to the deterioration of its properties. After the thermal aging, the DC breakdown strength decreased by 38% and 20% in the pure XLPE and its nanocomposite, respectively. Thermally aged nanocomposite shows negligible hetero charges and an increase in the DC conductivity by one order. However, the pure XLPE shows higher hetero charge accumulation and the increased DC conductivity by one order. In un‐aged XLPE nanocomposite higher crystallinity, higher deep trap density, and the lower carbonyl index are found to be the primary attributes of its improved performance. It is postulated that these significantly unchanged attributes can be the reason for the better anti‐thermal aging properties of the XLPE nanocomposite.