Rigidifying Ag(I) Complexes for Selective Nitrene Transfer

One of the challenges in achieving tunable and predictable C−H bond amidation via silver‐catalyzed nitrene transfer (NT) is the conformational flexibility and dynamic nature of many Ag(I) complexes. This fluxional behavior can make it difficult to obtain a clear understanding of the factors responsi...

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Bibliographic Details
Published in:ChemCatChem 2020-06, Vol.12 (11), p.3076-3081
Main Authors: Huang, Minxue, Paretsky, Jon, Schomaker, Jennifer M.
Format: Article
Language:English
Subjects:
allylic amines
benzyl amine
Bonding
Catalysts
Hydrogen bonds
nitrene transfer
Piperidine
propargylamines
Selectivity
Silver
Substrates
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