Analyzing the coloration of sodium borate glasses caused by sulfur species

Herein, coloration in sodium borate glasses containing sulfur were investigated and sulfur species in the glasses were determined using ultraviolet–visible (UV–vis), Raman, and fluorescence spectroscopy. Sample coloration varied from blue to brown and depended on alkali content and glass matrix comp...

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Bibliographic Details
Published in:Journal of the Ceramic Society of Japan 2020/09/01, Vol.128(9), pp.648-652
Main Authors: ASAHI, Taro, KISHIDA, Riho, NAKAYAMA, Susumu, WADA, Noriyuki
Format: Article
Language:English
Subjects:
Absorption spectra
Anions
Borate glass
Color centers
Composition
Fluorescence
Glass
Raman spectroscopy
Sodium borates
Spectrum analysis
Sulfur
UV–vis spectroscopy
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Summary:Herein, coloration in sodium borate glasses containing sulfur were investigated and sulfur species in the glasses were determined using ultraviolet–visible (UV–vis), Raman, and fluorescence spectroscopy. Sample coloration varied from blue to brown and depended on alkali content and glass matrix composition. Using UV–vis spectroscopy, several absorption bands were detected at 280, 380, and 580 nm. It was anticipated that the sulfur species, such as S2, S2−, and S3−, will be formed in the glass samples and will influence sample coloration. Raman spectroscopy suggested that the absorption band at approximately 580 nm was due to the S3− anion species, whereas fluorescence spectroscopy suggested that the absorption band at approximately 380 nm was due to S2− anion species. The ratio of these sulfur anion species varied with matrix glass compositions and had a strong effect on the sample coloration. Herein, the origin of these color centers is discussed from the viewpoint of the redox of the melt and borate glass network.
ISSN:1882-0743
1348-6535
DOI:10.2109/jcersj2.20111