Unsaturated binuclear homoleptic nickel carbonyl anions Ni2(CO)n− (n = 4–6) featuring double three-center two-electron Ni–C–Ni bonds

The homoleptic homodinuclear nickel carbonyl anions Ni2(CO)n− (n = 4–6) are mass-selected in the gas phase and examined with anion photoelectron velocity-map imaging spectroscopy combined with density functional calculations. The doubly carbonyl-bridged structures are found to be favorable for Ni2(C...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2020-11, Vol.22 (41), p.23773-23784
Main Authors: Liu, Zhiling, Bai, Yan, Li, Ya, He, Jing, Lin, Qingyang, Xie, Hua, Tang, Zichao
Format: Article
Language:English
Subjects:
Anions
Carbon monoxide
Carbonyls
Nickel carbonyl
Photoelectrons
Quantum chemistry
Vapor phases
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