Recovery of pentoses-containing olive stones for their conversion into furfural in the presence of solid acid catalysts

• Published in: Process safety and environmental protection 2020-11, Vol.143, p.1-13
• Main Authors: Fúnez-Núñez, I., García-Sancho, C., Cecilia, J.A., Moreno-Tost, R., Serrano-Cantador, L., Maireles-Torres, P.
• Format: Article
• Language: English
• Subjects: Acids; Aluminum oxide; Calcium chloride; Catalysts; Dehydration; Furfural; Hemicellulosic liquors; Hydrolysis; Lignocellulosic biomass; Niobium oxides; Olive stones; Organic acids; Solid acid catalysts; Transitional aluminas; Xylose; Xylose dehydration; Zirconium
• ISSN: 0957-5820; 1744-3598
• DOI: 10.1016/j.psep.2020.06.033

[Display omitted] •Furfural was obtained by autohydrolysis and subsequent dehydration of pentoses.•Efficient recovery of pentoses was carried out by autohydrolysis of olive stones.•High furfural efficiency was attained by using these liquors with Al2O3 and CaCl2.•The highest acid density of Al2O3 provided better catalytic performances.•Acetic and lactic acids promoted side reactions, decreasing furfural production. Olive stones were employed as feedstock for furfural production in two stages: 1) autohydrolysis of hemicellulosic fraction to recover their pentoses, mainly xylose, and 2) subsequent dehydration of pentoses into furfural. Autohydrolysis step was optimized by using different experimental conditions (temperature: 160−200 °C and time: 30−75 min), giving rise to liquors with different xylose concentrations, since hydrolysis was incomplete in some cases. The combined use of a commercial γ-Al2O3 and CaCl2 led to total hydrolysis of non-hydrolyzed pentosans after autohydrolysis step, and the subsequent dehydration of pentoses into furfural. The maximum values of furfural yield and efficiency were 23 and 96 %, respectively, after only 60 min at 150 °C by using liquor obtained by autohydrolysis at 180 °C and 30 min (L5.1) as source of pentoses. This liquor, L5.1, provided better catalytic results than other liquors which had shown higher xylose concentration after autohydrolysis, probably due to these latter also exhibited a higher concentration of organic acids; thus, the presence of organic acids, such as acetic and lactic acids, could promote undesired reactions leading to lower furfural yields. Finally, γ-Al2O3 was more effective for furfural production under these experimental conditions than other solid acid catalysts, such as mesoporous Nb2O5, Nb-doped SBA-15 and Zr-doped HMS silicas, probably due to alumina has a higher density of acid sites.