A Local D4h Symmetric Dysprosium(III) Single‐Molecule Magnet with an Energy Barrier Exceeding 2000 K

Three six‐coordinate DyIII single‐molecule magnets (SMMs) [Dy(OtBu)2(L)4]+ with local D4h symmetry are obtained by optimizing the equatorial ligands. One of the compounds with L=4‐phenylpyridine shows an energy barrier (Ueff) of 2075(11) K, which is the third largest Ueff, and the first Ueff>2000...

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Bibliographic Details
Published in:Chemistry : a European journal 2021-02, Vol.27 (8), p.2623-2627
Main Authors: Ding, Xia‐Li, Zhai, Yuan‐Qi, Han, Tian, Chen, Wei‐Peng, Ding, You‐Song, Zheng, Yan‐Zhen
Format: Article
Language:English
Subjects:
Anisotropy
Chemistry
D4h symmetry
Dysprosium
energy barrier
Magnetic anisotropy
Magnets
single-molecule magnets
six-coordinate
Symmetry
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