Properties and Assessment of Applications of Red Mud (Bauxite Residue): Current Status and Research Needs

• Published in: Waste and biomass valorization 2021-03, Vol.12 (3), p.1185-1217
• Main Authors: Reddy, Peddireddy Sreekanth, Reddy, Narala Gangadhara, Serjun, Vesna Zalar, Mohanty, Bijayananda, Das, Sarat Kumar, Reddy, Krishna R., Rao, Bendadi Hanumantha
• Format: Article
• Language: English
• Subjects: Alkalinity; Aluminum; Bauxite; Bayer process; Engineering; Environment; Environmental Engineering/Biotechnology; Industrial Pollution Prevention; Industrial wastes; Leaching; Literature reviews; Metal industry; Mineralogy; Natural resources; pH effects; Properties (attributes); Red mud; Renewable and Green Energy; Residues; Review; Waste Management/Waste Technology; Waste materials
• ISSN: 1877-2641; 1877-265X
• DOI: 10.1007/s12649-020-01089-z

In order to conserve natural resources and prevent waste generation, effective utilization of industrial wastes and/or by-products for beneficial engineering applications becomes inevitable. In order to accomplish this, extensive research studies, exploring properties and new applications of waste materials in a sustainable and environmentally friendly manner, have been initiated worldwide. Red mud (RM, also known as bauxite residue) is one of the wastes generated by the aluminium industry and its disposal and utilization have been traditionally hindered due to the extreme alkalinity (pH about 10.5–13.5). To date, no comprehensive review on various properties of RM of different origin and associated challenges in using it as a beneficial engineering material has been performed. The objective of this study is first to critically appraise the current understanding of properties of RM through a comprehensive literature review and detailed laboratory investigations conducted on Indian RM by the authors, to assess and identify the potential engineering applications, and to finally discuss associated challenges in using it in practical applications. Physical, chemical, mineralogical and geotechnical properties of RMs of different origin and production processes are reviewed. Mechanisms behind the pozzolanic reaction of RM under different chemical and mineralogical compositional conditions are discussed. Environmental concerns associated with the use of RM are also raised. Studies relevant to leachability characteristics reveal that most of the measured chemical concentrations are within the permissible regulatory limits. Overall, the review shows that RM disposal and reuse is complicated by its extreme alkalinity, which is also noticed to be influencing multiple engineering properties. But with selected pH amendments, the treated RM is found to have significant potential to be used as an effective and sustainable geomaterial. The assessment is majorly based on the characteristics of Indian RMs; hence the adaptation of the findings to other RMs should be assessed on a case-by-case basis. Moreover, field studies demonstrating the performance of RM in various engineering applications are warranted. Graphic Abstract