An investigation of the mixed water/formamide solvent on the synthesis of cadmium nitroprusside particles and its behavior in the electrochemical sensing of isoniazid

• Published in: Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2021-02, Vol.23 (2), Article 55
• Main Authors: Souza, Tamires Rocha, de Sá, Acelino Cardoso, do Carmo, Devaney Ribeiro
• Format: Article
• Language: English
• Subjects: Cadmium; Characterization and Evaluation of Materials; Chemistry and Materials Science; Electrochemistry; Inorganic Chemistry; Isoniazid; Lasers; Materials Science; Microparticles; Nanoparticles; Nanotechnology; Optical Devices; Optics; Oxidation; Photonics; Physical Chemistry; Raman spectroscopy; Research Paper; Scanning electron microscopy; Solvents; Spectroscopy; Spectrum analysis; X-ray diffraction
• ISSN: 1388-0764; 1572-896X
• DOI: 10.1007/s11051-021-05152-1

Size-controlled cadmium nitroprussides, with particles in the micron meter or submicron size range (0.050–1.15 micron), (CdNPs) were prepared from total and varied compositions of water and formamide solvent in the complexation reaction of cadmium and nitroprusside ions. Four analytical systems (CdNP-1, CdNP-2, CdNP-3, and CdNP-4) were set up. The coordinated materials were investigated by spectroscopic and analytical techniques such as Raman spectroscopy, ultraviolet-visible spectroscopy (UV-Vis), X-ray diffraction (XRD), scanning electron microscopy (SEM), and cyclic voltammetry (CV). The CVs of the modified graphite paste electrode with CdNP-1, CdNP-2, CdNP-3, and CdNP-4 (10% m/m) exhibited a defined redox pair with formal potential ( E θ′ ) = 0.63 ± 0.02 V ( ν = 20 mV s −1 ; KNO 3 1.0 M). The dependence of particle size on the isoniazid electro-oxidation was verified by CdNP-3 and CdNP-4 microparticles. Graphical abstract