Sintering behaviors and properties of porous ceramics derived from artificially cultured diatom frustules

Bimodal porous ceramics with high strength have been fabricated by conventional powder metallurgy utilizing artificially cultured diatom frustules (DFs). The effect of sintering temperature on thermal behaviors, phase transition, and pore structures features of DFs‐based porous ceramics is investiga...

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Bibliographic Details
Published in:Journal of the American Ceramic Society 2021-05, Vol.104 (5), p.2378-2387
Main Authors: Lyu, Sha, Wang, Yanjing, Huang, Jintao, Li, Tao, Li, Dandan, Wang, Jaw‐Kai, Zhang, Jiangtao, Sun, Dazhi, Yu, Peng
Format: Article
Language:English
Subjects:
Ceramic powders
Ceramics
Compressive strength
Cristobalite
diatom frustule
High strength
Infrared spectroscopy
Multilayers
phase transition
Phase transitions
Porosity
porous ceramic
Powder metallurgy
Sintering
Sintering (powder metallurgy)
Thermal analysis
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Summary:Bimodal porous ceramics with high strength have been fabricated by conventional powder metallurgy utilizing artificially cultured diatom frustules (DFs). The effect of sintering temperature on thermal behaviors, phase transition, and pore structures features of DFs‐based porous ceramics is investigated between 800 and 1200°C. The phase evolution of DFs powders is investigated with thermal analysis (DIL and DSC‐TG). Phase transition behaviors analyzed with XRD, Raman, and FT‐IR spectra confirm the transformation of quartz into cristobalite phases occurs under 1050°C. Sintering under 950°C could bind DFs powders tightly into high strength porous ceramics while maintain the multilayer pore structures simultaneously, having porosity of 56.4%, compressive strength of 15.0 MPa and surface area of 50.9 m2/g, respectively. Slit‐shaped microstructures and mesopores (2‐50 nm) are observed in DFs‐based porous ceramics sintered under 1050°C. Collapse and blockage of pore structures as well as partial fusion of DFs particles happened at the temperature of 1100°C, indicating the presence of diminished multilayers and particle agglomeration.
ISSN:0002-7820
1551-2916
DOI:10.1111/jace.17611