Pore engineering of Co3O4 nanowire arrays by MOF-assisted construction for enhanced acetone sensing performances

• Published in: Sensors and actuators. B, Chemical Chemical, 2021-02, Vol.329, p.129095, Article 129095
• Main Authors: Xu, Keng, Lai, Chun, Yang, Yanxing, Zhou, Hang, Zhou, Chengwu, Yang, Yong, Yu, Ting, Yuan, Cailei
• Format: Article
• Language: English
• Subjects: Acetone; Arrays; Co3O4 array; Cobalt oxides; Gas sensing; Gas transport; Metal oxides; Metal-organic frameworks; Miniaturization; MOF; Nanowires; Operating temperature; Oxidation; Porosity; Porous structure; Recovery time; Sensor arrays; Sensors; Substrates; Surface area; Surface reactions
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2020.129095

•The porosity of Co3O4 arrays were regulated by constructing and oxidizing of ZIF-67 on their surface.•The porous Co3O arrays with the highest porosity and surface area exhibited the highest response to acetone.•This strategy can pave a new way to improve the gas-sensing properties of array film-based sensors. Array-based sensors have been regarded as excellent candidates for the gas-sensing elements owing to their low-cost preparation, great miniaturization potential as well as stable performance. However, it still remains a great challenge to prepare porous arrays and regulate their porosity to increase pores for gas transport and active sites for surface reactions. To solve this problem, the porosity of metal oxide arrays (Co3O4) that had grown directly in-situ on the surface of ceramic substrates was regulated by the constructing and oxidizing of MOFs (ZIF-67) that coated on the surface cobalt-containing precursor arrays. It was found that the porosity and surface area of Co3O4 nanowire arrays increased with the content of ZIF-67. The porous Co3O arrays with the highest porosity and surface area exhibited the highest response value (Rg/Ra = 16.7), the lowest optimal operating temperature (200 °C) as well as the fastest response/recovery time (4/39 s) towards acetone. These porous Co3O4 arrays are thus promising gas-sensing materials for acetone detection with excellent performances. This novel strategy to enhance the porosity of arrays can pave a new way to improve the gas-sensing properties of array film-based sensors.