Spin–Electric Coupling in a Cobalt(II)‐Based Spin Triangle Revealed by Electric‐Field‐Modulated Electron Spin Resonance Spectroscopy

A cobalt(II)‐based spin triangle shows a significant spin–electric coupling. [Co3(pytag)(py)6Cl3]ClO4⋅3 py crystallizes in the acentric monoclinic space group P21. The intra‐triangle antiferromagnetic interaction, of the order of ca. −15 cm−1 (H=−JSaSb), leads to spin frustration. The two expected e...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2021-04, Vol.60 (16), p.8832-8838
Main Authors: Kintzel, Benjamin, Fittipaldi, Maria, Böhme, Michael, Cini, Alberto, Tesi, Lorenzo, Buchholz, Axel, Sessoli, Roberta, Plass, Winfried
Format: Article
Language:English
Subjects:
Anisotropy
Antiferromagnetism
Cobalt
Communication
Communications
Coupling
Coupling (molecular)
Crystals
Electric fields
Electric properties
Electron paramagnetic resonance
Electron spin resonance
electron spin resonance spectroscopy
Magnetic anisotropy
magnetic properties
Resonance
Single crystals
Spectroscopy
Spectrum analysis
Spin resonance
spintronics
spin–electric effect
Symmetry
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