Direct growth and size tuning of InAs/GaAs quantum dots on transferable silicon nanomembranes for solar cells application

• Published in: Journal of materials science. Materials in electronics 2021-07, Vol.32 (13), p.18251-18263
• Main Authors: Aouassa, Mansour, Franzò, Giorgia, M’Ghaieth, Ridha, Chouaib, Hassen
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemical vapor deposition; Chemistry and Materials Science; Crystal structure; Crystallinity; Energy gap; Foils; High resolution electron microscopy; High vacuum; Indium arsenides; Materials Science; Microscopy; Optical and Electronic Materials; Optical properties; Photoluminescence; Photovoltaic cells; Porous silicon; Quantum dots; Silicon; Sintering (powder metallurgy); Solar cells; Strain; Substrates; Thickness
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-021-06368-6

In this paper we show for the first time the possibility to direct grow and tune the size and optical properties of high quality InAs/GaAs quantum dots on transferable crystalline silicon nanomembranes. The transferable silicon nanomembranes have been grown via in-situ H 2 prebake of porous silicon in Ultra High Vacuum Chemical vapour Deposition (UHV-CVD) reactor. Flat and continuous transferable crystalline nanomembranes with thicknesses below 30 nm have been obtained. The mechanical strain in the silicon nanomembranes has been tuned via sintering temperature between 900 and 1100 °C for the direct crystalline growth of transferable InAs/GaAs (QDs)/Si foils. The size and band gap energy of these InAs/GaAs quantum dots are tuned via strain engineering in silicon nanomembranes. Several advanced techniques such as Scanning Electron Microscopy (SEM), High-Resolution Transmission Electron Microscopy (HR-TEM), X-Ray Diffraction (XRD), Photoluminescence (PL) spectroscopy are used to investigate the structural and optical properties of transferable silicon nanomembranes and the grown InAs/GaAs QDs. High quality InAs/GaAs QDs with tuned sizes grown on flat and continuous transferable crystalline nanomembranes have been obtained. The obtained results have shown that this novel process allows the growth of well separated InAs/GaAs QDs with well defined shape, high density around 2 × 10 10 /cm 2 and a well controlled size variation as function of the substrate strain between 2 and 10 nm. The high quality of the structural and optical properties of the InAs/GaAs QDs monolithically grown on a transferable Si nanomembranes and its compatibility with standard Si solar cells technologies offer a great opportunity for growing a cheap and high performance InAs/GaAs quantum dots/Si third generation solar cells and microelectronic devices.