Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate

A series of sterically demanding α‐diimine ligands bearing electron‐donating and electron‐withdrawing substituents were synthesized by an improved synthetic procedure in high yield. Subsequently, the corresponding Pd complexes were prepared and isolated by column chromatography. These Pd complexes d...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2015-08, Vol.54 (34), p.9948-9953
Main Authors: Dai, Shengyu, Sui, Xuelin, Chen, Changle
Format: Article
Language:English
Subjects:
Acrylates
Acrylics
Catalysts
chain-walking polymerization
Column chromatography
Copolymerization
Copolymers
Density
Diimide
diimine ligands
Ethylene
Molecular weight
Palladium
palladium catalysis
polar monomers
Polyethylene
Polyethylenes
Polymerization
Polymers
Thermal stability
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