Size and doping effects on the improvement of the low-temperature magnetic properties of magnetically aligned cobalt ferrite nanoparticles

• Published in: Journal of alloys and compounds 2022-02, Vol.894, p.162432, Article 162432
• Main Authors: Tancredi, Pablo, Rivas-Rojas, Patricia C., Moscoso-Londoño, Oscar, Muraca, Diego, Knobel, Marcelo, Socolovsky, Leandro M.
• Format: Article
• Language: English
• Subjects: Cobalt ferrite; Cobalt ferrites; Coercivity; Diameters; High coercivity; Hot-injection synthesis; Iron; Low temperature; Magnetic anisotropy; Magnetic measurement; Magnetic nanoparticles; Magnetic properties; Nanoparticles; Remanence; Structural analysis
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2021.162432

•CoxFe3−xO4 NPs are synthesized by a thermal decomposition continuous growth approach.•The size and composition of the NPs are controlled by the reaction conditions.•Freezing the NPs in an oriented condition leads to a remanence and coercivity enhancement.•The enhancement of the magnetic properties depends on the structure of the NPs.•At the oriented condition, the “hardest” NPs reaches coercive fields of ≈ 30 kOe at 5 K. [Display omitted] The macroscopic magnetic behavior of nanoparticulated systems is the result of several contributions, ranging from the intrinsic structural properties of the nanoparticles to their spatial arrangement within the material. Unravelling and understanding these influences is an important task to produce nano-systems with improved properties for specific technological applications. In this work we study how the magnetic behavior of a set of magnetically hard nanoparticles can be improved by the modification of the sample arrangement (either randomly or magnetically oriented) and the nature of the enclosing matrices. At first, we employed a hot-injection, continuous growth strategy to synthesize non-stoichiometric cobalt ferrite (CoxFe3−xO4) nanoparticles. We prepared five batches of hydrophobic, oleate-coated samples, with mean diameters of 8 nm, 12 nm, 16 nm and variable Co-to-Fe proportions. The structural characterization confirms that the nanoparticles have a spinel-type monocrystalline structure and that the Co and Fe ions are homogenously distributed within the system. The magnetic properties of the nanoparticles were measured by DC magnetometry, and we found that the strategy used in this work to create a system of magnetically oriented nanoparticles can lead to a significant remanence and coercive field enhancement at low temperatures when compared with randomly oriented and fixed systems. The modification of the magnetic properties was detected in the five batches of samples, but the strength of the enhancement depends on both size and composition of the nanoparticles. Indeed, for the “hardest” samples the coercive field of the magnetically oriented systems reached values of around 30 kOe (3 T), which represents a 50% increase regarding the randomly oriented system and are among the highest reported to date for a set of Fe and Co oxide nanoparticles.