Kinetics of Carbon Partitioning of Q&P Steel: Considering the Morphology of Retained Austenite

• Published in: Metals (Basel ) 2022-02, Vol.12 (2), p.344
• Main Authors: Xu, Yaowen, Chen, Fei, Li, Zhen, Yang, Gengwei, Bao, Siqian, Zhao, Gang, Mao, Xinping, Shi, Jun
• Format: Article
• Language: English
• Subjects: Carbon; Chemical partition; Computer simulation; Cooling; Diffusion; Finite element method; Heat treating; Heat treatment; High strength steels; Kinetics; Martensite; Mathematical models; Morphology; Partitioning; Retained austenite; Simulation; Steel; Thermal simulators
• ISSN: 2075-4701; 2075-4701
• DOI: 10.3390/met12020344

The diffusion of carbon atoms from martensite to retained austenite (RA) is controlled by the carbon partitioning kinetics when the quenching and partitioning (Q&P) process is conducted. The RA is divided into film-like and blocky ones in morphology. This research aims to study the influence of the morphology of RA on the kinetics of carbon partitioning mainly by developing a numerical simulation. A one-step Q&P process was modeled at the partitioning temperature of 330–292 °C, with a partitioning time ranging from 10−6 to 5 × 103 s. The finite element method was employed to solve the carbon diffusion equation. A thermomechanical simulator Gleeble-3500 was used to conduct the corresponding Q&P heat treatment, and the RA was examined by X-ray diffraction. The results show that the film-like RA will be enriched in carbon within a short time at first, followed by a decrease in carbon concentration due to the massive absorption of carbon by blocky RA, leading the stable film-like RA to become unstable again. The end of the kinetics of carbon partitioning was the concentration determined by the constrained carbon equilibrium (CCE) model, provided that the CCE condition was employed in this study. It took quite a long time (thousands of seconds) to complete the carbon partitioning globally, which was influenced by the partitioning temperature.