Effect of Temperature of Long Annealing on the Structure and Magnetic Properties of Nanocrystalline FeSiNbCuB Alloy

• Published in: Physics of the solid state 2021-07, Vol.63 (7), p.978-991
• Main Authors: Ershov, N. V., Chernenkov, Yu. P., Lukshina, V. A., Smirnov, O. P., Shishkin, D. A.
• Format: Article
• Language: English
• Subjects: Analysis; Anisotropy; Annealing; Atomic structure; Curie temperature; Diffraction; Diffraction patterns; Ferrosilicon; Ferrous alloys; Hysteresis loops; Iron silicide; Magnetic hysteresis; Magnetic properties; Magnetism; Nanocrystals; Phase composition; Physics; Physics and Astronomy; Solid State Physics; Specialty metals industry; Stoichiometry; Temperature effects; X-ray diffraction; X-rays
• ISSN: 1063-7834; 1090-6460
• DOI: 10.1134/S1063783421070076

The dependence of soft magnetic properties of the Fe 73.5 Si 13.5 Nb 3 Cu 1 B 9 alloy on the 2-hour air annealing temperature T an at temperatures from 520 to 620°C is studied. It is shown that the magnetic hysteresis loop is significantly broadens and becomes more inclined, and the Curie temperature of the amorphous matrix surrounding α-FeSi nanocrystals decreases with increasing T an . The atomic structure and phase composition of alloy samples are studied by transmission X-ray diffraction. After annealing at temperatures to 580°C, nanocrystals contain mostly D 0 3 phase (Fe 3 Si stoichiometry) and are ~7 nm in average size. Their relative fraction in the alloy increases with temperature due to additional iron diffusion from the matrix to nanocrystals. After annealings at T an > 600°C, the average nanocrystal size increases, and iron boride crystal reflections appear in X-ray diffraction patterns. Degradation of soft magnetic properties of nanocrystalline Fe 73.5 Si 13.5 Nb 3 Cu 1 B 9 alloy with annealing temperature from 520 to 580°C is explained by a decrease in the silicon concentration in FeSi nanocrystals, which results in an increase in the magnetocrystalline anisotropy.