H2O in omphacite of quartz and coesite eclogite from Erzgebirge and Fichtelgebirge, Germany

• Published in: Journal of metamorphic geology 2022-05, Vol.40 (4), p.665-686
• Main Authors: Gose, Jürgen, Schmädicke, Esther
• Format: Article
• Language: English
• Subjects: Absorption spectra; Amphiboles; Banded structure; Breakdown; Coesite; Composition; Dehydration; Eclogite; Erzgebirge; Garnet; Garnets; Inclusions; Mineral composition; Minerals; omphacite; Peak pressure; Quartz; structural H2O; Subduction; Titanium dioxide; Trace elements; Zirconium
• ISSN: 0263-4929; 1525-1314
• DOI: 10.1111/jmg.12642

Major and trace elements in omphacite, including hydrogen, were determined in eclogites from two Variscan basement complexes in Germany: Erzgebirge (EG) and Fichtelgebirge (FG). Erzgebirge eclogite is derived from three units, showing different peak pressure (P) and temperature (T) conditions (Unit 1: 840–920°C/≥30 kbar, Unit 2: 670–730°C/24–26 kbar, Unit 3: 600–650°C/20–22 kbar). The peak conditions of FG eclogite (690–750°C/25–28 kbar) resemble those of EG Unit 2. Coesite eclogite occurs in EG Unit 1, and quartz eclogite in all other units. Omphacite from all samples shows four infrared (IR) absorption bands. Two prominent, sharp bands occur at 3,455 ± 10 cm−1 (band II) and 3,522 ± 10 cm−1 (band III). Band II is usually more prominent than band III, except for few samples with low jadeite content. A further, broad band is centred between 3,270 and 3,370 cm−1 (band I) and a fourth, minor band at 3,611–3,635 cm−1 (band IV). Bands II and III are due to hydrogen bound as structural OH− ions in omphacite. In most cases, this also applies to band IV. However, some spectra with extremely large type IV bands reflect phengite inclusions. The ambiguous band I may be due to different H2O species (molecular water, structural OH, and water in phengite). Omphacite of quartz eclogite has lower contents of TiO2, Zr, Hf, and REE, compared with that from coesite eclogite. By contrast, omphacite in quartz eclogite from both EG (H2O sample averages: 465–852 ppm) and FG (546–1,089 ppm) contains the same amount of structural OH (concentrations given in wt.‐ppm H2O) as omphacite in coesite eclogite (492–1,140 ppm). The obtained difference in the garnet‐omphacite H2O partition coefficient between quartz (0.01–0.03) and coesite eclogite (0.08–0.11) results from different H2O contents in garnet (coesite eclogite: 50–150 ppm; quartz eclogite: