Using polystyrene spheres to produce thin, porous interlayers in alumina laminates

• Published in: International journal of applied ceramic technology 2022-05, Vol.19 (3), p.1453-1461
• Main Authors: Daniel Barros, Marcelo, Hotza, Dachamir, Jelitto, Hans, Janßen, Rolf
• Format: Article
• Language: English
• Subjects: Alumina; Aluminum oxide; Bulk modulus; ceramic laminates; Colloiding; Crack propagation; Diamond pyramid hardness tests; Fracture toughness; Grain size; Interlayers; Laminates; mechanical strength; Modulus of elasticity; Polystyrene resins; porosity; R‐curve; Sintering (powder metallurgy); Thickness
• ISSN: 1546-542X; 1744-7402
• DOI: 10.1111/ijac.13980

Porous alumina layers were produced by colloidal processing of alumina with the addition of 15, 30, and 45 vol% polystyrene spheres (PS) as pore formers. Alumina laminates were designed with dense layers alternated with porous interlayers using 45 vol% of PS spheres and sintered at 1350°C. The layers’ thickness ranged from 2 to 15 μm, with a random distribution of pores. The higher volume fraction of pores tends to decrease the alumina average grain size, but does not influence the final size of bulk and surface pores. The obtained values of hardness and Young's modulus for the porous interlayer are ∼30% of the values obtained for the dense layer. Vickers indentations suggested that crack propagation can be opposed by the porous interlayers. However, values of mechanical strength, fracture toughness (KIC), and work of fracture presented no relevant difference compared to a monolithic reference. R‐curves presented a slight increase and KIC a decrease due to crack propagation through the porous interlayers. Although no macrodeviations of the crack path were observed in the fractured surfaces, microdeviations were detected in the interlayer regions.