Fast CO2 hydration kinetics impair heterogeneous but improve enzymatic CO2 reduction catalysis

The performance of heterogeneous catalysts for electrocatalytic CO 2 reduction suffers from unwanted side reactions and kinetic inefficiencies at the required large overpotential. However, immobilized CO 2 reduction enzymes—such as formate dehydrogenase—can operate with high turnover and selectivity...

Full description

Saved in:
Bibliographic Details
Published in:Nature chemistry 2022-04, Vol.14 (4), p.417-424
Main Authors: Cobb, Samuel J., Badiani, Vivek M., Dharani, Azim M., Wagner, Andreas, Zacarias, Sónia, Oliveira, Ana Rita, Pereira, Inês A. C., Reisner, Erwin
Format: Article
Language:English
Subjects:
639/638/161/886
639/638/224/685
639/638/45/607/1168
639/638/77/886
Analytical Chemistry
Biochemistry
Carbon dioxide
Carbon dioxide concentration
Carbonic anhydrase
Carbonic anhydrases
Catalysis
Catalysts
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dehydrogenase
Dehydrogenases
Electrocatalysts
Formate dehydrogenase
Hydration
Hydrogen evolution
Immobilization
Inorganic Chemistry
Kinetics
Organic Chemistry
Physical Chemistry
Reduction
Selectivity
Side reactions
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!