Modeling of Flux Reaction and Mixing in Continuous Casting Mold of Medium Mn Steel

• Published in: Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2022-06, Vol.53 (3), p.1516-1525
• Main Authors: Yang, Jie, Wang, Linjie, Li, Yang, Wang, Tongjun, Kong, Lingzhong, Zang, Ximin
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Composition; Continuous casting; Diffusion rate; Fluid dynamics; Fluid flow; Interface reactions; Iron and steel making; Liquid metals; Manganese oxides; Manganese steels; Materials Science; Metallic Materials; Mold fluxes; Nanotechnology; Nozzle flow; Original Research Article; Silicon dioxide; Solidification; Structural Materials; Surfaces and Interfaces; Thin Films; Three dimensional models
• ISSN: 1073-5615; 1543-1916
• DOI: 10.1007/s11663-022-02461-1

The interfacial reaction between molten steel and mold flux causes MnO accumulation and SiO 2 reduction in the mold flux during the continuous casting of medium Mn steel. A three-dimensional reaction model in the mold has been developed which coupled species transport with fluid flow, heat transfer and solidification. The model was applied to characterize the interfacial reaction and composition distribution of mold flux during the casting process. The model predictions were validated by comparison with experimental and plant measurements. The results show that the mold flux is driven by the surface flow of molten steel to form a high-speed circulating flow zone of mold flux at a distance 110 to 220 mm away from the mold’s narrow face, in which the reaction rate is high because of the fast interface update, which increases the time for the reaction with the molten steel and the components’ diffusion in the liquid flux pool. The mold flux near the nozzle flows slowly, allowing more time for interfacial reaction and component diffusion. The concentration of MnO in the molten flux pool decreases from the nozzle to the narrow face of the mold. The solid flux film is formed by the mixing and solidification of liquid mold fluxes with different MnO accumulations in different reaction stages, so that the MnO concentration in the solid film is lower than that of the liquid mold flux. The model predictions provide a basis for explaining the difference in composition of the mold flux film in the continuous casting of medium Mn steel.