Photoelectron spectroscopy of low valent organophosphorus compounds, P–CH3, H–P=CH2 and P=CH2

We report the mass-selected slow photoelectron spectra of three reactive organophosphorus species, P=CH2, and the two isomers, methylenephosphine or phosphaethylene, HP=CH2 and methylphosphinidine, P–CH3. All spectra were recorded by double imaging photoelectron–photoion coincidence spectroscopy (i2...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2022-05, Vol.24 (18), p.10993-10999
Main Authors: Mukhopadhyay, Deb Pratim, Gerlach, Marius, Hartweg, Sebastian, Fischer, Ingo, Loison, Jean-Christophe
Format: Article
Language:English
Subjects:
Atomic properties
Fluorine
Isomers
Nuclear reactors
Organophosphorus compounds
Phosphines
Photoelectrons
Quantum chemistry
Spectra
Spectroscopy
Spectrum analysis
Synchrotron radiation
Synchrotrons
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