Profiling hot isostatically pressed canister–wasteform interaction for Pu‐bearing zirconolite‐rich wasteforms

• Published in: Journal of the American Ceramic Society 2022-08, Vol.105 (8), p.5359-5372
• Main Authors: Dayal, Pranesh, Farzana, Rifat, Zhang, Yingjie, Lumpkin, Gregory R., Holmes, Rohan, Triani, Gerry, Gregg, Daniel J.
• Format: Article
• Language: English
• Subjects: Ceramics; Diffusion; Hot isostatic pressing; interfaces; Nickel; Pu‐bearing nuclear waste; radioactive waste; Scanning electron microscopy; Stainless steels; Synroc; Thickness
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/jace.18458

Zirconolite‐rich full ceramic wasteforms designed to immobilize Pu‐bearing wastes were produced via hot isostatic pressing (HIP) using stainless steel (SS) and nickel (Ni) HIP canisters. A detailed profiling of the elemental compositions of the major and minor phases over the canister–wasteform interaction zone was performed using scanning electron microscopy combined with energy‐dispersive X‐ray spectroscopy (SEM‐EDS) characterization. Bulk sample analyses from regions near the center of the HIP canister were also conducted for both samples using X‐ray diffraction and SEM‐EDS. The sample with the Ni HIP canister showed almost no interaction zone with only minor diffusion of Ni from the inner wall of the canister into the near‐surface region of the wasteform. The sample with the SS HIP canister showed ∼100–120 μm of interaction zone dominated by high‐temperature Cr diffusion from canister materials to the wasteform with the Cr predominantly incorporated into the durable zirconolite phase. We also examined, for the first time, changes to the HIP canister wall thickness caused by HIPing and demonstrated that no canister wall thinning occurred. Instead, in the areas examined, the canister wall thickness was observed to increase (up to ∼20%) due to the compression occurring during the HIP cycle. Further, only sparse formation of (Cr, Mn)‐rich oxide particles were noted within the HIP canister inner wall area immediately adjacent to the ceramic material, with no evidence for reverse diffusion of ceramic materials. Though the HIP canister–wasteform interaction extends to ∼120 μm when using an SS HIP canister for the system investigated, this translates to