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Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions
Oxidation of the N–phosphonomethyl iminodiacetic acid (PMIDA) with hydrogen peroxide in a two-phase system (aqueous phase—organic phase) in the presence of the [(Oct n ) 3 NMe] 3 {PO 4 [WO(O 2 ) 2 ] 4 } catalyst was studied and the kinetic parameters of this reaction were determined. It was found th...
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| Published in: | Catalysis letters 2022-07, Vol.152 (7), p.2025-2032 |
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| Main Authors: | , , |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c322t-887ce88af6e2eae13e0e1e49e41b2a5c8133ebaa27720a692d30bd066a9014583 |
| container_end_page | 2032 |
| container_issue | 7 |
| container_start_page | 2025 |
| container_title | Catalysis letters |
| container_volume | 152 |
| creator | Yushchenko, Dmitry Yu Pai, Zinaida P. Khlebnikova, Tatiana B. |
| description | Oxidation of the N–phosphonomethyl iminodiacetic acid (PMIDA) with hydrogen peroxide in a two-phase system (aqueous phase—organic phase) in the presence of the [(Oct
n
)
3
NMe]
3
{PO
4
[WO(O
2
)
2
]
4
} catalyst was studied and the kinetic parameters of this reaction were determined. It was found that the PMIDA oxidation with aqueous H
2
O
2
proceeds only in the presence of the catalyst giving PMIDA N-oxide as the main product. Under the studied conditions, the reaction orders with respect to the reagents (PMIDA and H
2
O
2
) and the catalyst were found to be the first. The apparent activation energy of the reaction for the temperature range of 313–343 K is 37 ± 3 kJ/mol.
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| doi_str_mv | 10.1007/s10562-021-03798-z |
| format | article |
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n
)
3
NMe]
3
{PO
4
[WO(O
2
)
2
]
4
} catalyst was studied and the kinetic parameters of this reaction were determined. It was found that the PMIDA oxidation with aqueous H
2
O
2
proceeds only in the presence of the catalyst giving PMIDA N-oxide as the main product. Under the studied conditions, the reaction orders with respect to the reagents (PMIDA and H
2
O
2
) and the catalyst were found to be the first. The apparent activation energy of the reaction for the temperature range of 313–343 K is 37 ± 3 kJ/mol.
Graphic Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-021-03798-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acids ; Activation energy ; Binary systems ; Catalysis ; Catalysts ; Catalytic oxidation ; Chemical tests and reagents ; Chemistry ; Chemistry and Materials Science ; Decomposition ; Hydrogen peroxide ; Industrial Chemistry/Chemical Engineering ; Kinetics ; Organometallic Chemistry ; Oxidation ; Oxidation-reduction reaction ; Physical Chemistry ; Reagents ; Solvents</subject><ispartof>Catalysis letters, 2022-07, Vol.152 (7), p.2025-2032</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>COPYRIGHT 2022 Springer</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c322t-887ce88af6e2eae13e0e1e49e41b2a5c8133ebaa27720a692d30bd066a9014583</citedby><cites>FETCH-LOGICAL-c322t-887ce88af6e2eae13e0e1e49e41b2a5c8133ebaa27720a692d30bd066a9014583</cites><orcidid>0000-0002-3366-9128</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Yushchenko, Dmitry Yu</creatorcontrib><creatorcontrib>Pai, Zinaida P.</creatorcontrib><creatorcontrib>Khlebnikova, Tatiana B.</creatorcontrib><title>Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Oxidation of the N–phosphonomethyl iminodiacetic acid (PMIDA) with hydrogen peroxide in a two-phase system (aqueous phase—organic phase) in the presence of the [(Oct
n
)
3
NMe]
3
{PO
4
[WO(O
2
)
2
]
4
} catalyst was studied and the kinetic parameters of this reaction were determined. It was found that the PMIDA oxidation with aqueous H
2
O
2
proceeds only in the presence of the catalyst giving PMIDA N-oxide as the main product. Under the studied conditions, the reaction orders with respect to the reagents (PMIDA and H
2
O
2
) and the catalyst were found to be the first. The apparent activation energy of the reaction for the temperature range of 313–343 K is 37 ± 3 kJ/mol.
Graphic Abstract</description><subject>Acids</subject><subject>Activation energy</subject><subject>Binary systems</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic oxidation</subject><subject>Chemical tests and reagents</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Decomposition</subject><subject>Hydrogen peroxide</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Kinetics</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Oxidation-reduction reaction</subject><subject>Physical Chemistry</subject><subject>Reagents</subject><subject>Solvents</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kc1uEzEURkcIJErgBVhZYsXCxT-Zsb2MIqARVRtBK3VnOfadjKvEDrYjmm54dTwdJNQNugvb1-dcW_qa5j0l55QQ8SlT0nYME0Yx4UJJ_PiiOaOtYFgKdfey7gmlmAt297p5k_M9IUQJqs6a3998gOJtRrFHV3g9xHwYYoh7KMNph1Z7H6Lzxo4MWljv0NIUszuNx-sH70zxMaBfvgzo4uRS3EJAa0ixXgG6DQ4SKgOg9WAy4JtkQu5raxmD86OZ3zaverPL8O7vOmtuv3y-WV7gy-uvq-XiElvOWMFSCgtSmr4DBgYoBwIU5grmdMNMayXlHDbGMCEYMZ1ijpONI11nFKHzVvJZ82Gae0jx5xFy0ffxmEJ9UrNO8pbwsWbN-URtzQ60D30sydhaDvbexgC9r_2FIFIpxmlbhY_PhMoUeChbc8xZr358f86yibUp5pyg14fk9yadNCV6TFFPKeqaon5KUT9WiU9SrnDYQvr37_9YfwCsH6Ee</recordid><startdate>20220701</startdate><enddate>20220701</enddate><creator>Yushchenko, Dmitry Yu</creator><creator>Pai, Zinaida P.</creator><creator>Khlebnikova, Tatiana B.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-3366-9128</orcidid></search><sort><creationdate>20220701</creationdate><title>Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions</title><author>Yushchenko, Dmitry Yu ; Pai, Zinaida P. ; Khlebnikova, Tatiana B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c322t-887ce88af6e2eae13e0e1e49e41b2a5c8133ebaa27720a692d30bd066a9014583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acids</topic><topic>Activation energy</topic><topic>Binary systems</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic oxidation</topic><topic>Chemical tests and reagents</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Decomposition</topic><topic>Hydrogen peroxide</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Kinetics</topic><topic>Organometallic Chemistry</topic><topic>Oxidation</topic><topic>Oxidation-reduction reaction</topic><topic>Physical Chemistry</topic><topic>Reagents</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yushchenko, Dmitry Yu</creatorcontrib><creatorcontrib>Pai, Zinaida P.</creatorcontrib><creatorcontrib>Khlebnikova, Tatiana B.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yushchenko, Dmitry Yu</au><au>Pai, Zinaida P.</au><au>Khlebnikova, Tatiana B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2022-07-01</date><risdate>2022</risdate><volume>152</volume><issue>7</issue><spage>2025</spage><epage>2032</epage><pages>2025-2032</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Oxidation of the N–phosphonomethyl iminodiacetic acid (PMIDA) with hydrogen peroxide in a two-phase system (aqueous phase—organic phase) in the presence of the [(Oct
n
)
3
NMe]
3
{PO
4
[WO(O
2
)
2
]
4
} catalyst was studied and the kinetic parameters of this reaction were determined. It was found that the PMIDA oxidation with aqueous H
2
O
2
proceeds only in the presence of the catalyst giving PMIDA N-oxide as the main product. Under the studied conditions, the reaction orders with respect to the reagents (PMIDA and H
2
O
2
) and the catalyst were found to be the first. The apparent activation energy of the reaction for the temperature range of 313–343 K is 37 ± 3 kJ/mol.
Graphic Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-021-03798-z</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-3366-9128</orcidid></addata></record> |
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| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2022-07, Vol.152 (7), p.2025-2032 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2683503030 |
| source | Springer Nature |
| subjects | Acids Activation energy Binary systems Catalysis Catalysts Catalytic oxidation Chemical tests and reagents Chemistry Chemistry and Materials Science Decomposition Hydrogen peroxide Industrial Chemistry/Chemical Engineering Kinetics Organometallic Chemistry Oxidation Oxidation-reduction reaction Physical Chemistry Reagents Solvents |
| title | Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions |
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