Oxidation states and occupation sites of Fe and Cu ions in the Y3Fe5−xCuxO12, (0.00 ≤ x ≤ 0.05) compound synthesized via sol gel method

• Published in: Journal of alloys and compounds 2022-09, Vol.915, p.165417, Article 165417
• Main Authors: Leal, L., Matilla-Arias, J., Guerra, Y., Oliveira, Carla S., Castro-Lopes, S., Viana, Bartolomeu C., Abreu, G., Mariño-Castellanos, P., Santos, F., Peña-Garcia, R.
• Format: Article
• Language: English
• Subjects: Cations; Coral-shaped; Crystal structure; Dopants; Electron diffraction; Energy distribution; Ferrous ions; Fourier transforms; Infrared spectroscopy; Oxidation; Oxidation state; Oxygen; Oxygen vacancies; Photoelectrons; Reticular energy; Sol gel; Sol-gel processes; Spectrum analysis; Valence; X ray photoelectron spectroscopy; YIG
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2022.165417

This paper presents an experimental and theoretical study on the oxidation states and occupation sites of Fe and Cu ions in the Y3Fe5−xCuxO12, (0.00 ≤ x ≤ 0.05) compound synthesized via sol gel method. Transmission electron microscopy images showed agglomerated coral-shaped particles, while selected area electron diffraction analysis confirmed the formation of YIG cubic structure, since the bright points correspond to the (004), (123), (024), (224), (022), and (112) YIG family planes. Fourier transform infrared and Raman spectroscopies testified the YIG crystal structure formation and suggest that the Fe by Cu replacement occurs in the octahedral sites. The cation distribution and reticular energy were estimated theoretically, revealing that the more probable valence state combination corresponds to Cu+-Fe2+ doped YIG configuration. The experimental study by X-ray Photoelectron Spectroscopy certified the elements valence states and confirmed that Y, Fe and Cu are mainly in the Y3+, Fe3+, Fe2+ and Cu+ oxidation states. The oxygen vacancies formation was also identified through the deconvolution of XPS spectra for the oxygen region. Finally, the dopant occupation probability per site as function of dopant concentration per unit formula was calculated using a phenomenological model and suggested that Cu+ and Fe2+ cations prefer to occupy the octahedral sites in the YIG crystal structure. •Cu-doped YIG nanoparticles were synthesized by the sol gel method.•Fe ions were found in the oxidation states 3+ and 2+.•Cu+ ions were discovered in Cu- doped YIG.•The cation distribution and reticular energy were estimated theoretically.•Cu+ and Fe2+cations are in the a-sites of YIG.