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Near‐Infrared and Dual Emissions of Diphenylamino Group‐Substituted Malachite Green Derivatives
Novel triarylmethanols and triarylmethyl cations with diphenylamino groups were designed and synthesized. The triarylmethyl cations exhibited near‐infrared (NIR) emission in toluene solution, solid film state, and polystyrene (PS) film. The emission intensities of the triarylmethyl cations were stro...
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Published in: | European journal of organic chemistry 2022-08, Vol.2022 (31), p.n/a |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Novel triarylmethanols and triarylmethyl cations with diphenylamino groups were designed and synthesized. The triarylmethyl cations exhibited near‐infrared (NIR) emission in toluene solution, solid film state, and polystyrene (PS) film. The emission intensities of the triarylmethyl cations were strongest in the PS film. The relative quantum yield of the PS film increased as the number of diphenylamino groups increased. In addition, triarylmethanols exhibit dual emission in their aggregated state owing to the intermolecular interactions between triphenyl amine moieties and/or hydroxy groups. These findings are interesting because NIR and dual emissions are not observed in the dimethylamino group‐substituted triarylmethyl cation, which is referred to as the “malachite green,” and the corresponding triarylmethanol, respectively.
Triarylmethyl cations with diphenylamino groups exhibited near‐infrared (NIR) emission in toluene, solid film state, and polystyrene film. Diphenylamino group‐substituted triarylmethanols exhibited dual emission in their aggregated state. These results are in sharp contrast to those of dimethylamino group‐containing triarylmethanols and triarylmethyl cations. |
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ISSN: | 1434-193X 1099-0690 |
DOI: | 10.1002/ejoc.202200873 |