Hexagonal Planar [B6H6] within a [B6H12] Borate Complex: Structure and Bonding of [(CpTi)2(μ‐ɳ6 : ɳ6‐B6H6)(μ‐H)6]

Isolation of planar [B6H6] is a long‐awaited goal in boron chemistry. Several attempts in the past to stabilize [B6H6] were unsuccessful due to the domination of polyhedral geometries. Herein, we report the synthesis of a triple‐decker sandwich complex of titanium [(Cp*Ti)2(μ‐η6 : η6‐B6H6)(μ‐H)6] (1...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2022-08, Vol.61 (35), p.n/a
Main Authors: Kar, Sourav, Bairagi, Subhash, Haridas, Anagha, Joshi, Gaurav, Jemmis, Eluvathingal D., Ghosh, Sundargopal
Format: Article
Language:English
Subjects:
Bonding strength
Boranes
Boron
Hexagonal Ring
Planar
Sandwich Compounds
Titanium
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