Hydrophobization of hair to improve the interfacial adhesion between hair and high‐density polyethylene

• Published in: Polymer engineering and science 2023-01, Vol.63 (1), p.219-229
• Main Authors: González Enriquez, Norma Daniela, Patiño‐Herrera, Rosalba, Catarino‐Centeno, Rafael, Palestino, Gabriela, Almendárez Camarillo, Armando, Pérez, Elías
• Format: Article
• Language: English
• Subjects: Acids; Adhesion; Analysis; bovine hair; Carboxylic acids; Cattle; Chemical properties; Composite materials; composites; Contact angle; Garbage; Hair; High density polyethylenes; human hair; Hydrophobicity; Mechanical properties; Monounsaturated fatty acids; Oleic acid; Polyethylene; Saturated fatty acids; Stearic acid; storage and loss modulus; Storage modulus; Weight reduction
• ISSN: 0032-3888; 1548-2634
• DOI: 10.1002/pen.26199

Concerned about environmental pollution, and aware of the comfort that polyethylene provides for daily human life, this work sought to replace a percentage of high‐density polyethylene (HDPE) with human or bovine hair. Hair is natural, abundant, light weight, non‐toxic, and disposed of as garbage. The main disadvantage of natural composites is the interfacial adhesion. To increase the interfacial adhesion between hair and HDPE, stearic acid or oleic acid was chemically anchored on the hair surface, which leads to an improved contact angle hysteresis and hydrophobicity. Dynamic‐mechanical properties of the composites were investigated focusing on the type of carboxylic acid used (stearic or oleic acid), hair length, hair type (human or bovine) and amount of hair used in the composite. Taking 40°C as a reference, using 15% of hair with a length of 1 ± 0.15 mm, the highest storage modulus value was obtained with HDPE with human hair modified with oleic acid, exceeding the value of the storage modulus of HDPE by 67.64%. Increasing storage modulus on composites indicates of interfacial interaction and chemical affinity improvement between hair and polyethylene.