Kinetic Study of the Oxidation of Hydrogen Sulfide and Ethyl Mercaptan with Molecular Oxygen in the Presence of an Ammonia Solution of Cobalt Phthalocyanine Derivatives

The main kinetic tendencies in the individual oxidation of hydrogen sulfide and simultaneous oxidation of hydrogen sulfide and ethyl mercaptan with molecular oxygen in the presence of an ammonia solution of a substituted cobalt phthalocyanine derivative have been studied. Kinetic equations for the i...

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Bibliographic Details
Published in:Kinetics and catalysis 2022-12, Vol.63 (6), p.773-780
Main Authors: Kornetova, O. M., Mazgarov, A. M., Vildanov, A. F., Nizamutdinova, G. B.
Format: Article
Language:English
Subjects:
Ammonia
Catalysis
Chemistry
Chemistry and Materials Science
Hydrogen sulfide
Kinetic equations
Oxidation
Oxygen
Physical Chemistry
Rate constants
Thiols
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Summary:The main kinetic tendencies in the individual oxidation of hydrogen sulfide and simultaneous oxidation of hydrogen sulfide and ethyl mercaptan with molecular oxygen in the presence of an ammonia solution of a substituted cobalt phthalocyanine derivative have been studied. Kinetic equations for the individual oxidation of hydrogen sulfide and simultaneous oxidation of hydrogen sulfide and ethyl mercaptan were obtained based on the experimental data, and the rate constants of the reactions were calculated.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158422060088