Experimental investigations on laminar burning velocity variation of CH4 + air mixtures at elevated temperatures with CO2 and N2 dilution

• Published in: Journal of thermal analysis and calorimetry 2023-03, Vol.148 (6), p.2517-2526
• Main Authors: Sampath, Subhashree, Jithin, E. V., Kumbhakarna, Neeraj, Kumar, Sudarshan
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Atmospheric models; Carbon dioxide; Chemistry; Chemistry and Materials Science; Dilution; High temperature; Inorganic Chemistry; Measurement Science and Instrumentation; Methane; Mixtures; Numerical prediction; Physical Chemistry; Polymer Sciences; Sensitivity analysis; Velocity
• ISSN: 1388-6150; 1588-2926
• DOI: 10.1007/s10973-022-11917-0

Experimental investigations have been performed to examine the role of CO 2 and N 2 dilution on the laminar burning velocity variation of CH 4  + air premixed mixtures at high mixture temperatures using the externally heated diverging channel method. The experiments on diluted CH 4  + air mixtures are carried out for various mixture equivalence ratios ( ϕ  = 0.8–1.2) at higher mixture temperatures (300–650 K) and atmospheric pressure. The numerical predictions using three extensively used chemical kinetic models (GRI Mech 3.0, FFCM-1 and Aramco 2.0) are used to delineate the effect of CO 2 and N 2 dilution on laminar burning velocity variation. The volume fraction of both the diluents, i.e., CO 2 and N 2 , is varied from 0 to 30% by volume distinctively in CH 4 fuel. The burning velocity is observed to decrease sharply with CO 2 dilution as compared to N 2 dilution case. Detailed sensitivity analysis is carried out to understand the role of various key reactions on the variation of laminar burning velocity of the mixture with dilution. FFCM-1 kinetic model shows a good agreement of the measured values of laminar burning velocity as compared to the kinetic models of Aramco 2.0 and GRI Mech 3.0 mechanisms at various mixture temperature and dilution conditions.