Kinetics of the liquid-phase oxidation of cyclooctene in the presence of MnO2

The kinetics of the liquid-phase oxidation of cyclooctene by molecular oxygen in the presence of a MnC2 catalyst is studied. It is found that MnC2 is an initiator of this reaction and has no effect on the steps of chain propagation and termination. The oxidation occurs by a radical chain mechanism w...

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Published in:Kinetics and catalysis 2000-07, Vol.41 (4), p.457-461
Main Authors: Chernyak, B. I., Nikipanchuk, M. V., Mishchenko, G. M., Trach, Yu. B., Pyrig, I. Yu
Format: Article
Language:English
Subjects:
Catalysts
Chains
Kinetics
Liquid phase oxidation
Liquid phases
Manganese dioxide
Oxygen
Reaction kinetics
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creator Chernyak, B. I.
Nikipanchuk, M. V.
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Pyrig, I. Yu
description The kinetics of the liquid-phase oxidation of cyclooctene by molecular oxygen in the presence of a MnC2 catalyst is studied. It is found that MnC2 is an initiator of this reaction and has no effect on the steps of chain propagation and termination. The oxidation occurs by a radical chain mechanism with the escape of radicals to the bulk of the reaction mixture. Radicals are formed by the interaction of the olefin with the solid catalyst surface. The kinetic parameters of the reaction are calculated.
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subjects Catalysts
Chains
Kinetics
Liquid phase oxidation
Liquid phases
Manganese dioxide
Oxygen
Reaction kinetics
title Kinetics of the liquid-phase oxidation of cyclooctene in the presence of MnO2
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