Constraining the complex refractive index of black carbon particles using the complex forward-scattering amplitude

• Published in: Aerosol science and technology 2023-07, Vol.57 (7), p.678-699
• Main Authors: Moteki, Nobuhiro, Ohata, Sho, Yoshida, Atsushi, Adachi, Kouji
• Format: Article
• Language: English
• Subjects: Absorption; Absorption cross sections; Aerosol absorption; Aerosols; Atmospheric aerosols; Atmospheric models; Black carbon; Black carbon aerosols; Boundary layers; Carbon; Carbon particles; Climate models; Constraining; Domains; Global aerosols; Hans Moosmüller; Incident radiation; Particle size distribution; Radiation; Refractive index; Refractivity; Scattering amplitude; Short wave radiation; Wavelengths
• ISSN: 0278-6826; 1521-7388
• DOI: 10.1080/02786826.2023.2202243

Black carbon is the largest contributor to global aerosol's shortwave absorption in the current atmosphere and is an important positive climate forcer. The complex refractive index, m = m r + im i , the primary determinant of the absorbed and scattered energies of incident radiation per unit volume of particulate material, has not been accurately known for atmospheric black carbon material. An accurate value at visible wavelengths has been difficult to obtain due to the black carbon's wavelength-scale irregularity and variability of aggregate shape, distribution in particle size, and mixing with other aerosol compounds. Here, we present a method to constrain a plausible (m r , m i ) domain for black carbon from the observed distribution of the complex forward-scattering amplitude S(0°). This approach suppresses the biases due to the above-mentioned complexities. The S(0°) distribution of black carbon is acquired by performing single particle S(0°) measurements in a water medium after collecting atmospheric aerosols into water. We demonstrate the method operating at λ = 0.633 μm for constraining the refractive index of black carbon aerosols in the north-western Pacific boundary layer. From the plausible (m r , m i ) domain consistent with the observed S(0°) distributions and the reported range of mass absorption cross-section, we conservatively select 1.95 + 0.96i as a recommendable value of the refractive index for uncoated black carbon at visible wavelengths. The recommendable value is 0.17 larger in m i than the widely used value 1.95 + 0.79i in current aerosol-climate models, implying a ∼16% underestimate of shortwave absorption by black carbon aerosols in current climate simulations.