The effect of zinc oxide nanoparticles on the weathering performance of wood‐plastic composites

• Published in: Coloration technology 2023-08, Vol.139 (4), p.430-440
• Main Authors: Durmaz, Sefa, Keles, Ozlem Ozgenc, Aras, Ugur, Erdil, Yusuf Ziya, Mengeloglu, Fatih
• Format: Article
• Language: English
• Subjects: Artificial weathering tests; Color; Composite materials; Flour; Fourier transforms; Infrared analysis; Jupiter; Load transfer; Mechanical properties; Nanoparticles; Performance evaluation; Photodegradation; Service life; Surface resistance; Ultraviolet radiation; Zinc oxide; Zinc oxides
• ISSN: 1472-3581; 1478-4408
• DOI: 10.1111/cote.12666

In recent years, wood‐plastic composites (WPCs) have become among the most popular engineering materials. Most of their usage areas are outdoors, where they encounter various damaging factors. The weathering conditions cause significant deterioration to WPC surfaces, which negatively influences their service life. In this study, zinc oxide nanoparticles at different concentrations (1%, 3%, 5%, 10%) were added to a high‐density polyethylene‐based WPC matrix. The effect of zinc oxide nanoparticles on the weathering performance of WPC was evaluated after 840 hours of an artificial weathering test. The highest colour changes (∆E*) were monitored with control samples exposed for 840 hours. Adding zinc oxide nanoparticles improved the ultraviolet (UV) resistance and decreased the colour changes. The wood flour content also affected the colour changes on the WPC surface. A combination of 10% zinc oxide nanoparticles and 50% wood flour content provided the lowest colour changes. The barrier effect of nanoparticles protected the WPC surfaces from UV light. Zinc oxide nanoparticles also positively affected the load transfer, which restricted the reduction in mechanical properties after the weathering test. The degradation on the surface of WPCs was also investigated using attenuated total reflectance‐Fourier Transform–infrared analysis. The changes in the characteristic bands of polymer and wood indicated that surface degradation was inevitable. Light and scanning electron microscopy images also demonstrated micro‐cracks and roughness on the surface of WPCs. It is concluded that UV degradation is unavoidable, but zinc oxide nanoparticles can improve surface resistance against weathering conditions.