Investigation into the development of novel lanthanide‐based luminescent colorants for application to textiles and paper materials

• Published in: Coloration technology 2023-10, Vol.139 (5), p.610-620
• Main Authors: Lewis, D. M., Broadbent, P. J., Rigout, M. L. A., Carr, C. M., Seaton, C. C., Swift, T.
• Format: Article
• Language: English
• Subjects: Cellulose acetate; Cellulose fibers; Chemical compounds; Color; Coordination compounds; Dyeing; Energy transfer; Europium; Inkjet printing; Ion emission; Ligands; Passports; Phosphorescence; Photoexcitation; Polyamide resins; Security; Surface stability; Textiles; Ultraviolet radiation
• ISSN: 1472-3581; 1478-4408
• DOI: 10.1111/cote.12675

This article describes the synthesis and application of lanthanide‐based luminophores for visualisation under short wavelength ultraviolet (UV) activation (typically 254 nm). Luminophores are chemical compounds which re‐emit light of longer wavelength than typical fluorescence and phosphorescence, following photoexcitation, because of efficient energy transfer from the ligands to the lanthanide ion emission levels. The luminophores described in this article are all derived from europium and terbium metal complexes and cover the complete colour gamut. Selection of appropriate ligands allows for water solubility or water insolubility (if required pigment or disperse “dye” applications). Similar to dyeing or printing processes, the anionic complexes can be applied to polyamide fibres or to cellulosic fibres, whereas dispersions of the non‐ionic complexes are suitable for polyester or cellulose acetate fibre application. The water‐soluble derivatives are also suitable for ink‐jet printing and the water‐insoluble derivatives are suitable for lithographic or intaglio paper printing. The novel complexes are excited by radiation below 300 nm and thus cannot be activated by sunlight (the earth's atmosphere prevents light below about 300 nm reaching the surface). Accordingly, the photo‐stability of the dyed materials and prints obtained is excellent. These materials could be used in security marking applications, for example bank‐notes and passports, where they could replace the current fluorophores that are rendered visible under near UV light (typically 365 nm) illumination but exhibit relatively poor photo‐stability. The development of an RGB (red, green and blue) colour palette for inkjet printing based on these innovative luminophores will significantly support the design of digitally printed security features.