Facile synthesis of spinel nickel–manganese cobaltite nanoparticles with high rate capability and excellent cycling performance for supercapacitor electrodes

• Published in: Journal of applied electrochemistry 2023-11, Vol.53 (11), p.2109-2123
• Main Authors: Hoang, Thao Thi Huong, Le The, Son, Maenosono, Shinya, Van, Tuan Nguyen, Do Thi, Huong Giang, Chun, Sang-Eun, Viet, Thu Tran, Van, Nguyen To
• Format: Article
• Language: English
• Subjects: Capacitance; Chemistry; Chemistry and Materials Science; Current density; Electrochemical analysis; Electrochemistry; Energy storage; Industrial Chemistry/Chemical Engineering; Manganese; Metal oxides; Nanoparticles; Nickel; Physical Chemistry; Research Article; Specific energy; Spinel; Supercapacitors; Synthesis; Transition metals
• ISSN: 0021-891X; 1572-8838
• DOI: 10.1007/s10800-023-01907-x

Nickel- and manganese-based spinel compounds have emerged as important candidates for electrochemical energy storage. In this study, a spinel nickel–manganese cobaltite (s-NMC) material was synthesized by facile hydrothermal/calcination route and the material exhibited remarkable pseudocapacitive behavior performance. The synthesized s-NMC material had a specific capacitance of 418.3 F g −1 at a scan rate of 10 mV s −1 (216.2 F g −1 at a current density of 1 A g −1 ) and retained 95% of its specific capacitance after 5000 charge–discharge cycles at a current density of 2 A g −1 . These excellent electrochemical properties are attributed to the simultaneous presence of three transition metals in the s-NMC material. The asymmetric supercapacitor device using s-NMC delivered a maximum specific energy density of 16.58 Wh kg −1 at a specific power density of 825 W kg −1 and maintains of ∼97% specific capacitance after 2000 cycles at a current density of 2 A g −1 . This study highlights that the diversification of transition metals in spinel-based metal oxides is an effective approach to enhance the electrochemical performances in resulting compound materials. Graphical abstract