Signature of Topological Semimetal in Harmonic-honeycomb ReO3

Transition-metal honeycomb compounds are capturing scientific attention due to their distinctive electronic configurations, underscored by the triangular-lattice spin-orbit coupling and competition between multiple interactions, paving the way for potential manifestations of phenomena such as Dirac...

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Published in:arXiv.org 2023-12
Main Authors: Han, Yifeng, Chen, Cui-Qun, Sun, Hualei, Zhao, Shuang, Long, Jiang, Liu, Yuxuan, Sun, Zhongxiong, Wang, Meng, Dong, Hongliang, Zhang, Ziyou, Chen, Zhiqiang, Chen, Bin, Dao-Xin Yao, Man-Rong, Li
Format: Article
Language:English
Subjects:
Anomalies
Crystallography
Evolution
External pressure
Paramagnetism
Phase transitions
Spin liquid
Spin-orbit interactions
Superconductivity
Temperature dependence
Transition metals
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Summary:Transition-metal honeycomb compounds are capturing scientific attention due to their distinctive electronic configurations, underscored by the triangular-lattice spin-orbit coupling and competition between multiple interactions, paving the way for potential manifestations of phenomena such as Dirac semimetal, superconductivity, and quantum spin liquid states. These compounds can undergo discernible pressure-induced alterations in their crystallographic and electronic paradigms, as exemplified by our high-pressure (HP) synthesis and exploration of the honeycomb polymorph of ReO3 (P6322). This HP-P6322 polymorph bears a phase transition from P6322 to P63/mmc upon cooling around Tp = 250 K, as evidenced by the evolution of temperature-dependent magnetization (M-T curves), cell dimension, and conductivity initiated by an inherent bifurcation of the oxygen position in the ab plane. Insightful analysis of its band structure positions suggests this HP-P6322 polymorph being a plausible candidate for Dirac semimetal properties. This phase transition evokes anomalies in the temperature-dependent variation of paramagnetism (non-linearity) and a crossover from semiconductor to temperature-independent metal, showing a temperature independent conductivity behavior below ~200 K. Under increasing external pressure, both the Tp and resistance of this HP-polymorph is slightly magnetic-field dependent and undergo a "V"-style evolution (decreasing and then increasing) before becoming pressure independent up to 20.2 GPa. Theoretical calculations pinpoint this anionic disorder as a probable catalyst for the decrement in the conductive efficiency and muted temperature-dependent conductivity response.
ISSN:2331-8422
DOI:10.48550/arxiv.2310.20341