Industrial-scale efficient alkaline water electrolysis achieved with sputtered NiFeV-oxide thin film electrodes for green hydrogen production

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2023-12, Vol.12 (1), p.46-474
• Main Authors: Ha, Quoc-Nam, Yeh, Chen-Hao, Gultom, Noto Susanto, Kuo, Dong-Hau
• Format: Article
• Language: English
• Subjects: Alkaline water; Anodizing; Catalysts; Electrocatalysts; Electrodes; Electrolysis; Feasibility studies; Green hydrogen; Hydrogen production; Intermediates; Intermetallic compounds; Iron compounds; Iron oxides; Leaching; Magnetron sputtering; Nickel compounds; Oxidation; Oxygen; Phase transitions; Raman spectroscopy; Synergistic effect; Thin films; Vanadium; Water splitting
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/d3ta05699f

We propose a magnetron sputtering technique to enhance HER and OER performance with a bifunctional vanadium-substituted NiFe-based catalyst electrode formed into a NiFeV-oxide thin film. The sputtering approach generates oxygen vacancies by creating nonstoichiometric oxidation phases, i.e. , Fe 3 O 4− x and VO 2− y . Operando Raman spectroscopy reveals a synergistic effect between active metal sites and oxygen vacancies to promote the formation of a reconstructed active layer, i.e. , NiFe(oxy)hydroxyl, during anodic oxidation. This phase transition optimizes the adsorption energy of water intermediates to accelerate the water splitting. Moreover, the leaching of vanadium also plays a vital role in the activation and surface restructuring processes of the NiFeV-oxide pre-catalyst during OER electrocatalysis. Feasibility studies for an NFV-0.7(−)|NFV-0.7(+) stack-cell electrolyzer indicate that it delivers a high current density of 1000 mA cm −2 at low cell potentials of 2.00 V (without cell heating) and 1.84 V (at 60 °C) and exhibits excellent stability at 1000 mA cm −2 over 100 h. Our work offers a new paradigm for designing efficient bifunctional electrocatalysts, holding great promise for industrial-scale water splitting. To mitigate electrocatalyst peel-off under high current conditions, sputtering technology is employed to craft bifunctional electrocatalyst films, specifically ternary NiFeV-oxide films with varied V compositions for enabling comprehensive alkaline water splitting in industrial applications.